Metal oxoalkoxides. Synthesis, properties and structures
Literature Information
The review surveys the pathways of formation of crystalline oligomeric oxoalkoxides M mO n(OR) p, which are products of partially controlled (or uncontrolled) hydrolysis, oxidation, thermal decomposition of mono- and bimetallic alkoxides of the ortho series M(OR) n and M mM 'n(OR) p or elimination of ethers from these compounds. The physicochemical properties of oxoalkoxides (solubility, the behaviour in solutions, volatility, etc.) differ considerably from the properties of the corresponding alkoxides. Hence, oxoalkoxides can be considered as immediate precursors of oxide materials produced by sol–gel technology. The M mO n(OR) p compounds are classified according to the sizes of associates. The crystal chemistry of alkoxides is discussed. The bibliography includes 249 references.
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Source Journal
Russian Chemical Reviews
Founded in 1932, Russian Chemical Reviews aims to publish timely and important review articles covering most aspects of modern chemistry, including: Chemical physics Physical chemistry Computational and theoretical chemistry Catalysis Coordination chemistry Analytical chemistry Organic, organometallic and organoelement chemistry Chemistry of macromolecules Applied chemistry Biochemistry, bio-organic chemistry and biomolecular chemistry Medicinal chemistry Materials chemistry, nanochemistry, nanostructures Environmental chemistry
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