Synthesis of aviation fuel from bio-derived isophorone
Literature Information
Courtney Ford Ryan, Cameron M. Moore, Juan H. Leal, Troy A. Semelsberger, Jenny K. Banh, Junqing Zhu, Charles S. McEnally, Lisa D. Pfefferle, Andrew D. Sutton
Using photochemical [2 + 2] cycloaddition, a cyclobutane dione was generated from isophorone, a condensate of bio-acetone. Hydrodeoxygenation of the dione yielded a mixture of polycyclic alkanes, whose high energy density is appropriate for high perfomance aviation applications. This work outlines a light-based approach to increase the energy density of a potential renewable carbon aviation fuel in high yields and high carbon efficiency without sacrificing performance.
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