Trans-dichloro-tris([5]trovacenyl)stannate(iv), electro- and magneto-communication across a Cl–Sn–Cl backbone

Literature Information

Publication Date 2007-07-23
DOI 10.1039/B703349D
Impact Factor 6.222
Authors

Christoph Elschenbroich, Feng Lu, Olav Burghaus, Clemens Pietzonka, Klaus Harms



Abstract

Reaction of [5]lithiotrovacene (TVC-Li) with tin dichloride affords the triradical complex (THF)3Li+[(TVC)3SnCl2]− which was characterized by X-ray crystallography, cyclic voltammetry, EPR spectroscopy and magnetic susceptometry; redox splittings δE1/2 (“electrocommunication”) and the exchange parameters JEPR and Jχ (“magnetocommunication”) attest to inter vanadium interactions mediated by the central tin atom.

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

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