Trans-dichloro-tris([5]trovacenyl)stannate(iv), electro- and magneto-communication across a Cl–Sn–Cl backbone
文献信息
Christoph Elschenbroich, Feng Lu, Olav Burghaus, Clemens Pietzonka, Klaus Harms
Reaction of [5]lithiotrovacene (TVC-Li) with tin dichloride affords the triradical complex (THF)3Li+[(TVC)3SnCl2]− which was characterized by X-ray crystallography, cyclic voltammetry, EPR spectroscopy and magnetic susceptometry; redox splittings δE1/2 (“electrocommunication”) and the exchange parameters JEPR and Jχ (“magnetocommunication”) attest to inter vanadium interactions mediated by the central tin atom.
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来源期刊
Chemical Communications
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
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