Unravelling the role of triisopropylphosphane telluride in Ag(i) complexes
Literature Information
Juan Carlos Pérez-Sánchez, Carmen Ceamanos, Raquel P. Herrera, M. Concepción Gimeno
The coordination chemistry of chalcogenide ligands has always attracted significant interest in the field of inorganic chemistry, especially for soft metals such as those of group 11. Despite the scarcity of research on phosphane tellurides, we report on the synthesis and characterisation of five novel silver complexes containing the phosphane telluride ligand, TeP(iPr)3, along with other ancillary ligands such as mono or diphosphanes. Spectroscopic studies were performed to investigate the behaviour of these complexes, including their redox properties, as demonstrated by the 1,1′-diphenylphosphaneferrocene (dppf) silver derivatives. Additionally, these complexes showcase remarkable rapid interchange equilibrium, revealing silver species with distinctive Ag2Te2 cores and a combination of bridging and terminal TeP(iPr)3 ligands. A promising avenue for further investigation and potential applications emerges.
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Source Journal
Inorganic Chemistry Frontiers
Inorganic Chemistry Frontiers publishes research articles, reviews, notes, comments and methods covering all areas of inorganic chemistry. Emphases are placed on interdisciplinary studies where inorganic chemistry and organometallic chemistry meet related areas, such as catalysis, biochemistry, nanoscience, energy and materials science. For publication in Inorganic Chemistry Frontiers, papers should report high-quality work of exceptional novelty, which will be of significant interest to the wide readership of the journal.
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