Cation exchange in an anionic metal–organic framework enhancing propylene/propane separation

Literature Information

Publication Date 2023-10-04
DOI 10.1039/D3CE00761H
Impact Factor 3.545
Authors

Xue Zhang, Hui-Juan Tang, Min Zeng, Rong Yang, Yu Wang, Kai-Jie Chen



Abstract

Highly selective adsorptive separation of propylene/propane (C3H6/C3H8) using metal–organic frameworks (MOFs) is a promising approach to reducing energy consumption in the chemical industry. Here, we report a 3D anionic MOF obtained by the exchange of dimethylamine cations with small K+ ions. 77 K N2 isotherms proved that the pore volume increased from 0.30 cm3 g−1 to 0.42 cm3 g−1 after ion exchange. Moreover, at near room temperatures (273 K and 298 K), both single-component gas adsorption capacity and selectivity of C3H6/C3H8 were enhanced. The C3H6/C3H8 separation potential was further confirmed by breakthrough experiments with equimolar C3H6/C3H8 mixtures. Similar separation properties were also observed in ethylene/ethane separation.

Source Journal

CrystEngComm

CrystEngComm
CiteScore: 5.5
Self-citation Rate: 7.7%
Articles per Year: 643

CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.

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