Ordered growth of hexagonal and monoclinic phases of MoTe2 on a sapphire substrate

Literature Information

Publication Date 2023-09-07
DOI 10.1039/D3CE00378G
Impact Factor 3.545
Authors

Edmund Dobročka, Tatiana Vojteková, Yuriy Halahovets, Michaela Sojková, Jana Hrdá, Marián Precner, Zhuo Chen, Yong Huang, Sergej Ražnjević, Zaoli Zhang, Martin Hulman



Abstract

The transition metal dichalcogenides have been studied for various applications in electronics, sensing, or spintronics. Molybdenum ditelluride, MoTe2, occurs in 3 crystal systems: hexagonal (2H), monoclinic (1T′), and orthorhombic (Td). Here we report on tellurisation of Mo and MoO3 thin films to 2H-MoTe2 and 1T′-MoTe2 thin layers on sapphire substrates, respectively. To study the phases, we employed diffraction patterns using grazing-incidence wide-angle X-ray scattering, conventional X-ray diffraction and transmission electron microscopy (TEM). Measurements of pole figures confirmed the presence of a biaxial texture of both 1T′ and 2H phases. In the hexagonal phase, we found two ensembles of biaxially oriented crystallites offset by 30 degrees between the two groups. On the other hand, in the monoclinic layer, the crystallites follow the six-fold symmetry of the (0001) sapphire surface.

Source Journal

CrystEngComm

CrystEngComm
CiteScore: 5.5
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CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.

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