The highly enantioselective catalytic aza-Morita–Baylis–Hillman reaction
文献情報
Fang-Le Hu, Min Shi
The highly enantioselective aza-Morita–Baylis–Hillman (aza-MBH) reaction is one of the most important reactions for the synthesis of optically active α-methylene-β-amino carbonyl compounds. The use of chiral phosphines or amines as organocatalysts can be envisaged for this catalytic asymmetric reaction. This mini review focuses on the important developments with regard to asymmetric aza-MBH reactions catalyzed by chiral phosphines or amines or even organometallic complexes in recent decades and also on the perspectives that these new developments offer.
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Organic Chemistry Frontiers
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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