The synthesis of amines by the homogeneous hydrogenation of secondary and primary amides
文献情報
Angel A. Núñez Magro, Graham R. Eastham, David J. Cole-Hamilton
Amides can be hydrogenated to amines using a catalyst prepared in situ from [Ru(acac)3] and 1,1,1-tris(diphenylphosphinomethyl)ethane; water is required to stabilize the catalyst and primary amines can only be formed (selectivity up to 85%) if ammonia is also present.
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