High-pressure induced guest-mediated gate opening behaviour of the Co-based framework ZIF-67

文献信息

发布日期 2023-11-22
DOI 10.1039/D3CE00979C
影响因子 3.545
作者

Isabelle M. Jones, Gemma F. Turner, Kari Pitts, Rees Powell, Alan Riboldi-Tunnicliffe, Rachel Williamson, Stephanie Boer, Lauren Allen, Stephen A. Moggach



摘要

High-pressure single crystal X-ray diffraction has been used to probe framework–guest interactions in the Co-based metal–organic framework ZIF-67 during compression in 4 : 1 MeOH : EtOH and liquid nitrogen (LN2) pressure-transmitting media. On increasing pressure, the structure undergoes a gate-opening phase transition, characterised by rotation of the 2-methylimidazolate ligand, at 1.57 GPa in MeOH : EtOH and at 0.43 GPa LN2. Adsorption of N2 occurred progressively with increasing pressure into 6 adsorption sites and resulted in the first documented instance of pressure-induced solvatochromism in ZIF-67.

来源期刊

CrystEngComm

CrystEngComm
CiteScore: 5.5
自引率: 7.7%
年发文量: 643

CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.

推荐供应商

德国罗姆贝格机械厂
英国瑞德威特有限公司
中国盐城禾佳化工有限公司
德国劳工技术塔斯勒(LTT)有限公司
中国江苏弘惠医药有限公司
中国天津市博创化工有限公司
中国山东合晖国际贸易有限公司
中国上海芯上工业科技有限公司
中国台州市椒江天一化工厂
奥地利伯恩多夫乐队
免责声明
本页面提供的学术期刊信息仅供参考和研究使用。我们与任何期刊出版商均无关联,也不处理投稿事宜。如有投稿相关咨询,请直接联系相关期刊出版商。
如发现页面信息有误,请发送邮件至 [email protected] 联系我们。我们将及时核实并处理您的问题。