A dual-emission Tb-based MOF induced by ESPT for ratiometric ammonia sensing

文献信息

发布日期 2023-11-10
DOI 10.1039/D3CE00902E
影响因子 3.545
作者

Yuming Zhao, Rudie Zhang, Cheng Xiao, Dan Yue, Bowen Qin, Jinhui Liu, Zhenling Wang, Yu Fu



摘要

A dual-emission ratiometric fluorescent sensor consisting of a Tb-based metal organic framework (MOF, Tb-DOBDC) has been developed based on an excited-state proton transfer (ESPT) response linker. Due to the ESPT process, Tb-DOBDC exhibits dual emission, which affords a crucial condition for the detection of ammonia as a ratiometric fluorescent sensor.

来源期刊

CrystEngComm

CrystEngComm
CiteScore: 5.5
自引率: 7.7%
年发文量: 643

CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.

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