Influence of Na+ on vaterite formation, content and yield using steamed ammonia liquid waste as a calcium source
文献信息
Xuewen Song, Xinrui Hua, Xiaomin Zhang, Yuxin Tuo, Yihan Su, Jianxiang Ma, Sicheng Mu, Tianxing Chen, Panyang He, Lianjing Ma, Cunjian Weng
In this paper, the effect of Na+ concentration on the crystalline phase, morphology, and content of vaterite in a system with different Ca2+ and CO32− ratios using steamed ammonia liquid waste as the calcium source was investigated, and the effect of Na+ on the yield of vaterite was studied systematically for the first time. The obtained products were characterized by powder X-ray diffraction (XRPD), scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, laser particle size analysis (LPSA), and so on. The results show that the variation of Na+ concentration in different Ca2+ and CO32− ratio systems has an effect on the particle size, morphology, content, and CaCO3 yield of vaterite. Thermogravimetric (TG) analysis indicates that Na+ is involved in forming CaCO3 but does not enter the interior of the vaterite crystals. Mechanistic analysis shows that changes in Na+ concentration can alter the initial pH of the reaction system and the conductivity of the solution, thus changing the processes such as early nucleation and crystal growth of vaterite as well as inhibiting the vaterite phase transition, which determines the particle size of the vaterite obtained. This study reveals to a certain extent the influence of Na+ on the early nucleation and crystal growth of vaterite and provides theoretical support for the realization of large-scale industrial production of vaterite.
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CrystEngComm

CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.