Multi-functional fluorescent probe for Hg2+, Cu2+ and ClO− based on a pyrimidin-4-yl phenothiazine derivative
文献信息
Jiena Weng, Qunbo Mei, Bin Zhang, Yuanzhi Jiang, Bihai Tong, Quli Fan, Qidan Ling
A multi-functional fluorescent probe based on PzDPM (10-ethyl-3,7-di(pyrimidin-4-yl)-10H-phenothiazine) for Hg2+, Cu2+ and ClO− has been synthesized and characterized. The probe comprises an electron-donating fluorophore core of 10-ethylphenothiazine and two Hg2+-specific chelating arms of pyrimidin-4-yl. The 10-ethylphenothiazine also acts as a Cu2+/ClO−-specific reactive moiety. PzDPM exhibits green fluorescence and selectively senses Hg2+/Cu2+ upon coordination/reaction in acetonitrile (MeCN), and behaves as a turn-off chemosensor or ratiometric chemodosimeter, respectively. On the other hand, PzDPM is very weakly emissive in aqueous solution but acts as an excellent turn-on chemodosimeter for ClO− in 1 : 4 (v/v) MeCN : Tris–HCl (10 mM, pH = 7.0) with a maximum fluorescent intensity increase of over 110-fold. The probe PzDPM allows the determination of Hg2+, Cu2+ and ClO− at 10−7 M levels with satisfactory selectivity.
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