2,5-Dimethyl-2,5-bis[(2-methyl-2-propanyl)peroxy]hexane(CAS号:78-63-7)

2,5-二甲基-2,5-二(叔丁基过氧基)己烷

基本信息

2,5-Dimethyl-2,5-bis[(2-methyl-2-propanyl)peroxy]hexane

CAS号

78-63-7

分子式

C16H34O4

分子量

290.44 g/mol

EINECS号

201-128-1

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基本物理性质

熔点

6 °C

沸点

55-57°C7mm Hg(lit.)

密度

0.877g/mLat 25°C(lit.)

水溶性

immiscible

闪点

149°F

折射率

n20/D 1.423(lit.)

蒸气压

0.002Pa at 20℃

SMILES

CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C

InChI

InChI=1S/C16H34O4/c1-13(2,3)17-19-15(7,8)11-12-16(9,10)20-18-14(4,5)6/h11-12H2,1-10H3

InChIKey

DMWVYCCGCQPJEA-UHFFFAOYSA-N

LogP

4.817200000000005

拓扑极性表面积

36.92 Ų

氢键供体/受体

0 / 4

复杂度

252

分类与用途

化学分类

用途

用作硅橡胶、聚氨酯橡胶、乙丙胶和其他橡胶的硫化剂;也可用作聚乙烯交联剂和不饱和聚酯的硬化剂。该品没有二叔丁基过氧化物容易气化和过氧化二异丙苯产生臭味的缺点。是乙烯基硅橡胶有效的高温硫化剂,制品的抗张强度和硬度均高,拉伸和压缩变形也比较低。该品有毒,易燃易爆,属一级危险品。;又名双二五101硫化剂(DHBP-95),作乙烯基硅橡胶用有效的高温硫化剂,聚乙烯橡胶、乙丙橡胶的交联剂,能提高制品的拉伸强度和硬度,而伸长率及压缩变形均低, 硫化后的气味在烷基过氧化物中最微小。其用法可于混炼时加入胶料中混合使用。;用于硅橡胶、聚胺酯橡胶、乙丙橡胶和其他橡胶的硫化剂,也可用作聚乙烯交联剂和不饱和聚酯的硫化剂。本品没有二叔丁基过氧化物容易气化和过氧化二异丙苯产生臭味的缺点,是乙烯基硅橡胶有效的高温硫化剂,制品的抗张强度和硬度均高,拉伸和压缩变形也比较低。;天然或合成橡胶的交联剂;热塑性聚烯烃的交联剂;用作聚合物的引发剂和降解剂,硅橡胶、聚氨酯橡胶、乙丙橡胶和其它橡胶的硫化剂

安全信息

查看安全信息

危险说明

H315,H319

危险类别

5.2

稳定性

Unstable. May contain an inhibitor. Incompatible with strong oxidizing agents, acids, reducing agents, organic materials, powdered metals.

将由乙炔与丙酮及氢氧化钾在二甲苯、丁醇溶剂中反应所得的产物经水解制得2,5-二甲基己炔二醇。反者经骨架镍催化,在2.5MPa压力下加氢制得2,5-二甲基己二醇,再将其用过氧化氢进行过氧化。过氧化反应在硫酸存在下进行,反应温度不超过15℃,反应产物过滤,用10%硫酸铵、7%碳酸氢钠洗涤,干燥,即得2,5-二甲基过氧化己烷。在硫酸存在下,再将其与叔丁醇(在30-35℃下)进行叔丁基化,反应产物分层、洗涤、干燥,过滤,即得硫化剂双25。工业品硫化剂双25的纯度≥80%。原料消耗(kg/t)丙酮 2000叔丁醇 910过氧化氢(42-48%) 2100

同义词与参考文献

英文

  • Varox Liquid
  • Luperco 101XL
  • Peroxide, (1,1,4,4-tetramethyl-1,4- butanediyl)bis[(1,1-dimethylethyl)
  • 2,5-Bis(tert-butylperoxy)-2,5-dimethylhexane
  • CHEMBL1874231
  • 2,5-dimethyl-2,5di(tert.butylperoxy) hexane
  • HC 4 (peroxide)
  • HEXANE, 2,5-DIMETHYL-2,5-DI(t-BUTYLPEROXY)-
  • NCGC00253942-01
  • NSC38203
  • Trigonox 101-101/45
  • NCGC00164156-01
  • Perhexa 2.5B
  • 2,5-Dimethyl-2,5-dis(tert-butylperoxy)hexane
  • FT-0610430
  • 2,5-bis(tert-butyldioxy)hexane
  • CCRIS 4626
  • 2,5-di(tert.-butyl peroxy)-2,5-dimethyl hexane
  • Luperco 101X45
  • DMWVYCCGCQPJEA-UHFFFAOYSA-N
  • peroxide, (1,1,4,4-tetramethyltetramethylene) bisOtert-butyl
  • 2,5-Dimethyl-2,5-bis(tert-butylperoxy)hexane
  • Hexane,5-dimethyl-2,5-di(tert-butylperoxy)-
  • UNII-923755EYY5
  • Luperox(R) 101XL45, 2,5-Bis(tert-butylperoxy)-2,5-dimethylhexane, blend with calcium carbonate and silica
  • EC 201-128-1
  • CR 05
  • Trigonox XQ 8
  • Kayahexa AD
  • Kayahexa AD 40C
  • 2,5-bis(t-butylperoxy)-2,5-dimethylhexane
  • DTXSID9025110
  • Lupersol 101XL
  • Perhexa 3M40
  • 923755EYY5
  • 2,5-di(tert-butylperoxy)hexane
  • WLN: 1X1&1&OOX1&1&2X1&1&OOX1&1&1
  • NSC 38203
  • Peroxide,1,4,4-tetramethyl-1,4-butanediyl)bis[(1,1-dimethylethyl)
  • 2,5-Dimethyl-2,5-di(tert-butyl peroxy)hexane
  • Hexane, 2,5-dimethyl-2,5-bis(t-butylperoxy)-
  • UN2155
  • Interox DHBP
  • VAROX DBPH
  • Peroxide, 1,1'-(1,1,4,4-tetramethyl-1,4-butanediyl)bis(2-(1,1-dimethylethyl)
  • Hexane, 2,5-dimethyl-2,5-di(tert-butylperoxy)-
  • Peroxide,1,4,4-tetramethyltetramethylene)bis[tert-butyl
  • Lupersol 101
  • SCHEMBL23327
  • 2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane
  • Varox 50
  • RC 4 (peroxide)
  • LS-1751
  • Luperox(R) 101, 2,5-Bis(tert-butylperoxy)-2,5-dimethylhexane, technical grade, 90%
  • (1,4,4-Tetramethyltetramethylene)bis[tert-butyl peroxide]
  • Varox DBPH 50
  • Varox
  • NA2155
  • Trigonox 101
  • 78-63-7
  • Q27271465
  • CAS-78-63-7
  • EINECS 201-128-1
  • Peroxide, (1,1,4,4-tetramethyltetramethylene)bis(tert-butyl
  • TC 8 (catalyst)
  • NSC-38203
  • Luperox 101
  • 2,5-bis(tert-butylhydroperoxy)hexane
  • 2,5-Bis(tert-butyldioxy)-2,5-dimethylhexane
  • Di-tert-butyl 1,1,4,4-tetramethyltetramethylene diperoxide
  • Tox21_300177
  • AKOS015912764
  • DTXCID005110
  • Peroxide, (1,1,4,4-tetramethyl-1,4-butanediyl)bis[(1,1-dimethylethyl)
  • AC-16097
  • NCGC00164156-02
  • Kayahexa AD 40
  • 2,5-Dimethyl-2,5-bis(tert-butyldioxy)hexane
  • Peroxide, (1,1,4,4-tetramethyl-1,4-butanediyl)bis((1,1-dimethylethyl)
  • 2,5-DI(TERT-BUTYLPEROXIDE)HEXANE
  • BRN 1863369
  • NA2156
  • Interox DHBP 45IC/G
  • H11786
  • 2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane, 93%
  • 2,5-Dimethyl-2,5-di(t-butylperoxy)hexane
  • Triqanox XQ 8
  • UN2156
  • CT 8 (crosslinking agent)
  • 2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane
  • 2,5-dimethyl-2,5-di(t-butyl peroxy)hexane
  • Perhexa 2.5B40
  • AD 40C
  • (1,1,4,4-Tetramethyltetramethylene)bis(tert-butyl peroxide)
  • 2,5-Dimethyl-2,5-bis(tert-butylhydroperoxy)hexane
  • 2,5-dimethyl-2,5-di(tert-butylperoxy) hexane
  • VAROX DBPH-50
  • luperox
  • LUPEROX 101XL
  • 2,5-DIMETHYL-2,5-BIS(TERT-BUTYLPEROXY)HEXANE
  • 2,5-DIMETHYL-2,5-DI(T-BUTYL-PEROXY)HEXANE
  • 2,5-Bis(tert-butylperoxy)-2,5-dimethylhexane, blend with calcium carbonate and silica
  • Dimethylditertiarybutylperoxyhexaneactive
  • Trigonox?101
  • 2,5-dimethyl-2,5-bis(tert-butylperoxy)hexane
  • ad40c
  • cr05
  • DPDH
  • kayahexaad
  • luperox101
  • perhexa25b
  • varox
  • varox50

中文

  • 2,5-二甲基-2,5-双(叔丁基过氧基)己烷
  • 2,5-二甲基-2,5-双(叔丁基过氧化)己烷
  • 双二五
  • 2,5-二甲-2,5-二(三級丁過氧)己烷
  • 2,5-二甲基-2,5-二叔丁基过氧化己烷(双二五101硫化剂DHBP-95)
  • 2,5-双(叔丁基)-2,5-二甲基己烷
  • 阿克苏诺贝尔 TRIGONOX101-SC8B /双二五硫化剂
  • 硫化剂双二五DHBP
  • 硫化剂双25
  • 硫化剂双二五
  • 双"2,5"硫化剂
  • 2,5-二甲基-2,5-二(叔丁基过氧基)己烷
  • 2,5-二甲基-2,5-双(过氧叔丁基)己烷
  • 2,5-二甲基-2,5-双(叔丁过氧基)己烷
  • 2,5-二甲基-2,5-双(特丁过氧)己烷
  • 2,5-二甲基-2,5-双-(叔丁基过氧)己烷
  • 双二五硫化剂
  • 2,5-二甲基-2,5-二(叔丁基过氧化)己烷
  • 2,5-二甲基2,5-双(叔丁基过氧基)
  • 硫化剂双-25
  • 双“2,5”硫化剂
  • 2,5-Bis(tert-butylperoxy)-2,5-双(叔丁基)-2,5-二甲基己烷
  • 2,5-二甲基-2,5-双(过氧化叔丁基)己烷
  • 双-2,5-己烷

EC_Number

201-128-1

CAS号

78-63-7

Customs_Code

29012990

推荐供应商

供应商名称 会员等级 认证状态 主要类别 最小订购量 操作
中国中国 - 昂得生化科技(上海)有限公司
墨西哥墨西哥 - Arch Química,S.A. de C.V.
中国中国 - 北京金源化学集团有限公司
墨西哥墨西哥 - Alkem de México,SA de C.V.
中国中国 - 海南普利制药有限公司
德国德国 - ABB AG
中国中国 - 斯百全化学(上海)有限公司
德国德国 - 卡尔蔡司自动检测有限公司

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