The physical and electronic properties of Metal–Organic Frameworks containing dipyridylthiazolo[5,4-d]thiazole

文献情報

出版日 2023-11-01
DOI 10.1039/D3CE00541K
インパクトファクター 3.545
著者

Shyam C. Pal, Carol Hua, Patrick W. Doheny, Thomas B. Faust, Cameron J. Kepert, Madhab C. Das



要旨

Five Metal–Organic Frameworks ({[M2(tdc)2(L)2]·2DMF}, tdc = 2,5-thiophenedicarboxylate, M = ZnII (1–Zn), CuII (1–Cu), MnII (1–Mn), {[Zn(oba)(L)]·DMF·H2O} (2–Zn), oba = 4,4′-oxybisbenzoate, and {[Zn2(bpdc)2(L)2]·L}, (3–Zn) bpdc = 4,4′-biphenyldicarboxylate) that incorporate the redox-active 2,5-dipyridylthiazolo[5,4-d]thiazole (DPTzTz) ligand (L) have been synthesised and their electronic properties elucidated. The ligand-based organic radicals were generated using in situ techniques and monitored using a suite of solid-state spectroelectrochemistry techniques. The absence of a near infra-red band (NIR), indicating through-space intervalence charge transfer (IVCT), in all analysed materials suggests that both the inter-ligand distance between cofacial TzTz moieties and the flexibility of the TzTz moiety affect the through-space IVCT.

掲載誌

CrystEngComm

CrystEngComm
CiteScore: 5.5
自己引用率: 7.7%
年間論文数: 643

CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.

おすすめサプライヤー

ドイツカールツァイス自動検査有限会社
ドイツPiller Industrieventilatoren GmbH
中国重庆宸城医药有限公司
ドイツHSTマシンバウ GmbH
チリINQUISA S.A.
ドイツSITA Messtechnik GmbH
ドイツVulkan-Verlag GmbH
イタリアブレンバナ・コストゥルツィニ・インダストリ株式会社
アメリカ合衆国オーシャンワーク
中国北京ランデン時代環境科技有限公司
免責事項
このページに表示される学術雑誌情報は、参考および研究目的のみを目的としています。当社は雑誌出版社とは提携しておらず、投稿の取り扱いも行っておりません。出版に関するお問い合わせは、各雑誌出版社に直接ご連絡ください。
表示されている情報に誤りがある場合は、[email protected] までご連絡ください。迅速に確認し、対応いたします。