Interfacial engineering of a polymer–MOF composite by in situ vitrification

文献情報

出版日 2020-03-09

DOI 10.1039/D0CC00664E

インパクトファクター 6.222

著者

Rijia Lin, Jingwei Hou, Mengran Li, Zhanke Wang, Lei Ge, Shichun Li, Zhonghua Zhu, Thomas D. Bennett, Vicki Chen

要旨

Non-stoichoimetric crystalline ZIF-62 was used as the filler for a 6FDA-DAM polyimide-based composite membrane. In situ melting and vitrification of ZIF-62 was then performed, to yield the ZIF-62 glass phase (agZIF-62), within the polymer matrix. Focus ion beam scanning electron microscopy (FIB-SEM), thermal characterisation and membrane separation tests demonstrate the filling of voids at the MOF/polymer interface from the liquid phase of ZIF-62.

掲載誌

Chemical Communications

CiteScore: 8.6

自己引用率: 4.7%

年間論文数: 2458

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