Strong circularly polarized luminescence of an octahedral chromium(iii) complex
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Carolin Dee, Francesco Zinna, Winald R. Kitzmann, Gennaro Pescitelli, Katja Heinze, Lorenzo Di Bari, Michael Seitz
The chiral spin–flip luminophore [Cr(ddpd)2]3+ can be resolved into enantiopure material by chiral HPLC. The corresponding enantiomers show very high luminescence dissymmetry factors of up to ∣glum ∣≈ 0.093 in circularly polarized luminescence (CPL) measurements for the “ruby-like” phosphorescence transition 2E/2T1 → 4A2 in the near-IR region around λ ≈ 775 nm.
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